MILD STEEL CORROSION INHIBITION IN ACIDIC MEDIA USING SARCOCEPHALUS LATIFOLIUS LEAVES EXTRACT
DOI:
https://doi.org/10.4314/jfas.1277Keywords:
Kinetics, Isotherms, Mild steel, Corrosion inhibition, Sarcocephalus latifolius, ThermodynamicsAbstract
At temperatures between 303K and 323K, three different concentrations of the methanol extract from Sarcocephalus latifolius were utilized to inhibit the corrosion of mild steel coupons in a 0.9M HCl solution. The plant extract adhered to the surface of mild steel metal under the investigated conditions, according to surface characterization techniques including SEM and FT-IR. It has been proven through weight loss trials in this work that the plant extract's ability to suppress growth improves with both an increase in its concentration and a decrease in temperature. The corrosion and inhibition processes were presented as being viable and spontaneous using thermodynamic parameters. Additionally, it was determined that the inhibitory process followed first order kinetics, with half-life values rising as plant extract concentration did. Calculated activation energy values and isotherm characteristics demonstrated that the process adheres to the physical adsorption mechanism.
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Meraghni M, Lanez T, Lanez E, Bechki L, Kennoufa A, Experimental and theoretical study on corrosion inhibition of mild steel by meso-tetraphenyl-porphyrin derivatives in acid solution. Journal of Electrochemical Science and Engineering. 2023, 13(2):217-229. https://doi.org/10.5599/jese.1400
Zaiz T, Lanez T. Corrosion inhibition of carbon steel xc70 in h2so solution by ferrocene derivative 3-(ferrocenylmethylamine)benzonitrile. Journal of fundamental and applied sciences. 2012, 4(2):38-47. https://doi.org/10.4314/jfas.v4i2.8
Zaiz T, Lanez T. Application of some ferrocene derivatives in the field of corrosion inhibition. Journal of Chemical and Pharmaceutical Research, 2012, 4(5):2678-2680
Al-Amiery AA, Mohamad AB, Kadhum AA, Shaker LM, Isahak WN, Takriff MS. Experimental and theoretical study on the corrosion inhibition of mild steel by nonanedioic acid derivative in hydrochloric acid solution. Scientific Reports. 2022, 12(1):1-21. https://doi.org/10.1038/s41598-022-08146-8.
El-Haddad MA, Bahgat Radwan A, Sliem MH, Hassan WM, Abdullah AM. Highly efficient eco-friendly corrosion inhibitor for mild steel in 5M HCl at elevated temperatures: experimental & molecular dynamics study. Scientific reports. 2019, 9(1):1-5. https://doi.org/10.1038/s41598-019-40149-w.
Dou Y, Li Z, Cheng J, Zhang Y. Experimental Study on Corrosion Performance of Oil Tubing Steel in HPHT Flowing Media Containing O2 and CO2. Materials (Basel). 2020, 13(22):5214. doi: 10.3390/ma13225214. PMID: 33218137; PMCID: PMC7698940.
Al-Baghdadi S, Gaaz TS, Al-Adili A, Al-Amiery AA, Takriff MS. Experimental studies on corrosion inhibition performance of acetylthiophene thiosemicarbazone for mild steel in HCl complemented with DFT investigation. International Journal of Low-Carbon Technologies. 2021, 16(1):181-8. https://doi.org/10.1093/ijlct/ctaa050.
Yang D, Feng X, Yan N, Wang Y, Lu L, Mei P, Chen W, Lai L. Corrosion Inhibition Studies of Benzoxazole Derivates for N80 Steel in 1 M HCl Solution: Synthesis, Experimental, and DTF Studies. Open Journal of Yangtze Oil and Gas. 2022, 7(2):101-23. doi: 10.4236/ojogas.2022.72007.
Ayuba AM, Abdullateef A. Investigating the corrosion inhibition potentials of Strichnos spinosa l. Extract on aluminium in 0.3 M hydrochloric acid solution. Journal of Applied Science and Environmental Studies. 2021, 4(1):4-1.
Beniken M, Driouch M, Sfaira M, Hammouti B, Ebn Touhami M, Mohsin M. Kinetic–thermodynamic properties of a polyacrylamide on corrosion inhibition for C-steel in 1.0 M HCl medium: part 2. Journal of Bio-and Tribo-Corrosion. 2018, 4(3):1-3. https://doi.org/10.1007/s40735-018-0152-1.
Ayuba AM, Abubakar M. Inhibiting aluminium acid corrosion using leaves extract of Guiera senegalensis. Journal of Fundamental and Applied Sciences. 2021, 13(2):634-56. hpp/dx.doi.org/10.4314/jfas.v13i2.1.
Vani R, Bhandari A, Jain YA. Inhibition Effects of Banana And Orange Peel Extract on the Corrosion of Bright Steel in Acidic Media. InIOP Conference Series: Materials Science and Engineering. 2021, 1065(1): 012029. IOP Publishing. https://doi.org/10.1088/1757-899X/1065/1/012029.
Salem Y. Evaluation of Inhibition Efficiency of Oak Galls Extract as a Green Corrosion Inhibitor of Archaeological Iron Artifacts in the Atmospheric Environment. Materials Research. 2020, 23. https://doi.org/10.1590/1980-5373-MR-2020-0354.
Barreto LS, Santos AM, de Almeida TF, Silva DR, Cotting F, Capelossi VR. Application of a Mix of Vegetables Residues as Inhibitor for Carbon Steel. Materials Research. 2021, 25. https://doi.org/10.1590/1980-5373-mr-2020-0440.
Muhammad SL. Corrosion inhibition of zinc in 0.5 M HNO3 using Azadirachta indica extract: Experimental and computational study. Bayero Journal of Pure and Applied Sciences. 2022, 13(1): 149-62. ISSN2006-6996. http://dx.doi.org/10.4314/bajopas.v13i1.1S.
Olufemi BA, Arowora T. Corrosion Inhibition of Mild Steel in Tetraoxosulphate (VI) Acid Using Mangifera Indica and Citrus Sinensis Peels Extracts. Journal of Science and Technology. 2020, 12(2):75-83. https://doi.org/10.30880/jst .2020.12.02.008.
Chauhan DS, Mazumder MJ, Quraishi MA, Ansari KR, Suleiman RK. Microwave-assisted synthesis of a new Piperonal-Chitosan Schiff base as a bio-inspired corrosion inhibitor for oil-well acidizing. International journal of biological macromolecules. 2020, 158:231-43. https:// doi. org/ 10. 1016/j. ijbio mac. 2020. 04. 195
Godwin-Nwakwasi EU, Elachi EE, Ezeokonkwo MA, Onwuchuruba LE. A Study of the Corrosion Inhibition of Mild Steel in 0.5 M Tetraoxosulphate (VI) acid by Alstonia boonei Leaves Extract as an Inhibitor at Different Temperatures. International Journal of Advanced Engineering, Management and Science. 2017, 3(12): 239950. https://doi.org/10.22161/ijaems.3.12.9.
Wang Q, Tan B, Bao H, Xie Y, Mou Y, Li P, Chen D, Shi Y, Li X, Yang W. Evaluation of Ficus tikoua leaves extract as an eco-friendly corrosion inhibitor for carbon steel in HCl media. Bioelectrochemistry. 2019, 128:49-55. https://doi.org/10.1016/j.bioelechem.2019.03.001.
Gupta DK, Awasthi L, Das AK, Yadav B, Ghimire A, Yadav AP. Corrosion Inhibition Effect of Acidic Extract of Bark of Eucalyptus Globulus on Mild Steel. Tribhuvan University Journal. 2020, 35(1):1-0. https://doi.org/10.3126/tuj.v35i1.35828.
Okewale AO, Adebayo T. Investigation of pumpkin pod extract as corrosion inhibitor for carbon steel in HCl Solution. Nigerian Journal of Technology. 2020, 39(1):173-81. doi: 10.4314/njt.v39i1.19.
Patrascu MT, Busuioc AD, Busuioc C, Cotarta A, Cojocaru A, Visan T, Vaireanu DI. Experimental Study on the Corrosion of Carbon Steel and Aluminum Alloy in Firefighting Protein Foam Concentrates. Materials. 2021, 14(23):7259. https://doi.org/10.3390/ma14237259.
Godwin-Nwakwasi EU, Elachi EE, Ezeokonkwo MA, Onwuchuruba LE. A Study of the Corrosion Inhibition of Mild Steel in 0.5 M Tetraoxosulphate (VI) acid by Alstonia boonei Leaves Extract as an Inhibitor at Different Temperatures. International Journal of Advanced Engineering, Management and Science. 2017, 3(12):239950. https://doi.org/10.22161/ijaems.3.12.9.

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