ELECTROCHEMICAL BEHAVIOR AND ANALYSIS OF MONURON HERBICIDE IN WATER USING VOLTAMMETRIC METHODS AND PRE ACTIVATED CARBON PASTE ELECTRODE
DOI:
https://doi.org/10.4314/jfas.v11i1.2Keywords:
Monuron electroanalysis; carbon paste electrode; anodic activation; square wave voltammetryAbstract
This research work dealt with the electrochemical behavior and voltammetric analysis of monuron, a phenyl urea herbicide. The sensitive enhancement of the monuron electrochemical signal, using a pre-activated carbon paste electrode, and the explanation of its mechanism were the main findings of this study. Unlike most used herbicides (linuron, diuron, fenuron, etc), monuron was rarely studied before by electrochemical methods. Indeed the square wave voltammetry allowed to optimize and to analyze monuron in water samples; the results showed two linear ranges of concentration: from 1.98 to 0.39 µg mL-1 and from 0.35 to 0.08 µg mL-1, with detection and quantification limits of LOD= 0.016 µg mL-1 and LOQ= 0.054µg mL-1 respectively. Besides these quantitative results, the anodic oxidation of monuron has been explained by an irreversible adsorption-controlled process, following a “one electron – one proton” mechanism.
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References
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[2] Navaratne A, Priyantha N, “Chemically Modified Electrodes for Detection of Pesticides,” Pesticides in the Modern World - Trends in Pesticides Analysis, Dr. M. Stoytcheva (Ed.), InTech, 2011, 453–464.
[3] Concialini V, Lippolis MT, Galletti GC,Analyst, 1989, 114(12), 1617–1619, doi:10.1039/AN9891401617
[4] Eichelberger JW, Lichtenberg JJ. Environ Sci Technol. 1971, 5(6), 541–544, doi:10.1021/es60053a002
[5] Kong L-G, Tan Z-C, Mei J-T, Sun L-X, Bao X-H. Thermochim Acta, 2004, 414(2), 131–135,doi:10.1016/j.tca.2003.12.007
[6] Dalgleish T, “Photosensitive Composition” J. Exp. Psychol. Gen., 2007,136(1), 23–42
[7] IARC. Agents Classified by the IARC Monographs , Volumes 1 – 104. IARC Monogr. 2012, 7(000050), 1–25.
[8] BlixP ,United States Patent, 1975, 19, doi: 10.1016/j.(73)
[9] World Health Organization, “The Who Recommended Classification of Pesticides By Hazard and Guidelines To Classification 2009,” World Heal. Organ., 2010, 1–60
[10] Katsumata H, Asai H, Kaneco S, Suzuki T, Ohta K,Microchemical Journal, 2007, 85(2), 285–289, doi: 10.1016/j.microc.2006.07.001
[11] Farrington DS, Hopkins RG, Talanta, 1977, 102, 377–381,doi:10.1039/AN9770200377
[12] Lourencetti C, de Marchi MRR, Ribeiro ML,Talanta, 2008, 77(2), 701–709, doi:10.1016/j.talanta.2008.07.013
[13] Rodrigues AM, Ferreira V, Cardoso VV, Ferreira E, Benoliel MJ, J. Chromatogr. A, 2007, 1150(2), 267–278,doi:10.1016/j.chroma.2006.09.083
[14] Ruberu SR, Draper WM, Perera SK.Journal of Agricultural and Food Chemistry,2000, 48(9), 4109-4115,doi: 10.1021/jf000266p
[15] Barroso MB, Konda LN, Morovjan G, HRC J. High Resolut, Chromatogr., 1999, 22(3), 171–176, doi: 10.1002/(SICI)1521-4168(19990301)22:3<171::AID-JHRC171>3.0.CO;2-Z
[16] Chicharro M, Bermejo E, Sánchez A, Zapardiel A, Fernandez-Gutierrez A, Arraez D.Anal. Bioanal. Chem., 2005, 382(2), 519–526,doi: 10.1007/s00216-004-2840-6
[17] Liu S, Zheng Z, Li X.Analytical and Bioanalytical Chemistry, 2013,405(1), 63–90, doi: 10.1007/s00216-012-6299-6
[18] Barek J, Fischer J, Navrtil T, PeckovK, Yosypchuk B, Zima J.Electroanalysis, 2007, 19(19–20), 2003–2014, doi: 10.1002/elan.200703918
[19] Siara LR, De Lima F, Cardoso CAL, Arruda GJ,Electrochim. Acta, 2015, 151, 609–618, doi:10.1016/j.electacta.2014.11.008
[20] Dordević J, Papp Z, Guzsvány V, Švancara I, Trtić-Petrović T, Purenović M, et al., Sensors, 2012, 12(1), 148–161,doi : 10.3390/s120100148
[21] De Lima F, Gozzi F, Fiorucci AR, Cardoso CAL, Arruda GJ, Ferreira VS, Talanta, 2011, 83(5), 1763–1768,doi:10.1016/j.talanta.2010.12.014
[22] Đorđević JS, Kalijadis AM, Kumrić KR, Jovanović ZM, Laušević Z V, Trtić-petrović TM, Cent. Eur. J. Chem.,2012, 10(4), 1271-1279, doi: 10.2478/s11532-012-0042-1
[23] Mani V, Devasenathipathy R, Chen SM, Wu TY, Kohilarani K, Ionics (Kiel)., 2015, 21(9), 2675–2683, doi:10.1007/s11581-015-1459-2
[24] Sharma P, Sablok K, Bhalla V, Suri CR, Biosens. Bioelectron., 2011, 26(10), 4209–4212, doi: 10.1016/j.bios.2011.03.019
[25] Švancara I, Vytřas K, Kalcher K, Walcarius A, Wang J, Electroanalysis, 2009,21(1), 7–28,doi:10.1002/elan.200804340
[26] Švancara I, Vyt K, Svancara I, Crit. Rev. Anal. Chem., 2010, 31(3), 37–41, doi: 10.1080/20014091076785
[27] Siara LR, De Lima F, Cardoso CAL, Arruda GJ, Electrochim. Acta, 2015, 151, pp. 609–618, 2015,doi: 10.1016/j.electacta.2014.11.008
[28] Hernandez P, Vicente J, Gonzalez M, Hernandez L, Talanta, 1990, 37(8), 789–794, doi:10.1016/0039-9140(90)80120-5
[29] Nady H, El-Rabiei MM, El-Hafez GMA, Egypt. J. Pet., 2017, 26(3), 669–678, doi:10.1016/j.ejpe.2016.10.009
[30] Arranz A, Fdez De Betoño S, Moreda JM, Arranz JF, Talanta, 1997, 45(2), 417–424, doi: 10.1016/S0039-9140(97)00155-0
[31] Laviron E, J. Electroanal. Chem., 1974, 52(3), 395–402,doi: 10.1016/S0022-0728(74)80449-3
[32] Luo S, Wu Y, Gou H, Ionics, 2013, 19(4), 673–680, doi:10.1007/s11581-013-0868-3
[33] Sharma P, Bhalla V, Tuteja S, Kukkar M, Suri CR, Analyst, 2012, 137(10), 2495, doi:0.1039/c2an16235k
[34] Mugadza T, Nyokong T, Talanta, 2010, 81(4–5), 1373–1379, doi: 10.1016/j.talanta.2010.02.037
[35] Benedito da Silva O, Machado S a. S, Anal. Methods, 2012, 4(8), 2348–2354, doi:10.1039/c2ay25111f
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Published
2018-11-14
How to Cite
ABDOU, I.; BOUHIDEL, K. E. ELECTROCHEMICAL BEHAVIOR AND ANALYSIS OF MONURON HERBICIDE IN WATER USING VOLTAMMETRIC METHODS AND PRE ACTIVATED CARBON PASTE ELECTRODE. Journal of Fundamental and Applied Sciences, [S. l.], v. 11, n. 1, p. 11–24, 2018. DOI: 10.4314/jfas.v11i1.2. Disponível em: https://jfas.info/index.php/JFAS/article/view/28. Acesso em: 27 jan. 2025.
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