CRYSTAL STRUCTURE AND HIRSHFELD ANALYSIS OF (C7H5NS)2SNCL6.2H2O

Authors

  • Oussama Chebout Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale (CHEMS), Faculté des Sciences Exactes, Université Constantine-1 25000, Algeria
  • M'hamed Boudraa Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale (CHEMS), Faculté des Sciences Exactes, Université Constantine-1 25000, Algeria
  • Hocine Merazig Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale (CHEMS), Faculté des Sciences Exactes, Université Constantine-1 25000, Algeria

DOI:

https://doi.org/10.4314/jfas.1237

Keywords:

Benzothiazole stannate, hydrogen bonds, single-crystal, X-ray diffraction, Hirshfeld surface.

Abstract

The compound bisbenzothiazolium hexacholoridostannate(II) dihydrate was obtained and structurally characterized by single-crystal X-ray diffraction techniques. The ionic compound crystallizes in the triclinic, space group P-1. The environment of the Sn ion is octahedral slightly deformed. Supramolecular architecture involves C—H…O, C—H…Cl and N—H…O hydrogen bonds and featuring p–p stacking interactions link the molecules into a three-dimensional network. Hirshfeld analysis was performed to show the intermolecular interactions in the crystal structure.  

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References

Farajia L., Shahkaramib S., Nadric H., Moradic A., Saeedid M., Foroumadia A., Ramazanib A., Haririane I., Ganjalif M. R., Shafieea A., Khoobia M. J. Chem. Res. 2017, 41: 30–35 https://doi.10.3184/174751917X14836231670980

Bouacida S., Merazig H., Beghidja A., Beghidja C. Acta Cryst. 2005, E61 : m2072-m2074

https://doi.org/10.1107/S1600536805029727

Bouacida S., Merazig H., Benard-Rocherulle P., Rizzoli C. Acta Cryst. 2007, E63: m379-m381

https://doi.org/10.1107/S160053680605656X

Bouacida S., Kechout H., Belhouas R., Merazig H., Roisnel T. Acta Cryst. 2011, E67: m395 https://doi.org/10.1107/S1600536811007252

Ali B. F., Al-Far R., Haddad S. F. Acta Cryst. 2008, E64: m637-m638 https://doi.org/10.1107/S160053680800901X

Pellerito L., Nagy L. Coord. Chem. Rev. 2002, 224: 111-150

https://doi.org/10.1016/S0010-8545(01)00399-X

Khan K. M., Rahim F., Halim S. A., Taha M., Khan M., Perveen S., Haq Z., Mesaik M. A., Choudhary M. I., Bioorg. Med. Chem. 2011, 19: 4286-4294

https://doi.org/10.1016/j.bmc.2011.05.052

Stone E. L., Citossi F., Singh R., Kaur B., Gaskell M., Farmer P.B., Monks A., Hose C., Stevens M. F. G., Leong C-O., Stocks M., Kellam B., Marlow M., Bradshaw T.D. Bioorg. Med. Chem. 2015, 23: 6891-6899 https://doi.org/10.1016/j.bmc.2015.09.052

Sener E. A., Arpaci O. T., Yalcin I., Altanlar N., Il Farmaco, 2000, 55: 397-405 https://doi.org/10.1016/S0014-827X(00)00059-8

Singh M. K., Tilak R., Nath G., Awasthi S.K., Agarwal A. Eur. J. Med. Chem. 2013, 63: 635-644 https://doi.org/10.1016/j.ejmech.2013.02.027

Bouchareb H., Benmebarek S., Bouacida S., Merazig H., Boudraa M. Acta Cryst. 2014, E70: m275 https://doi.org/10.1107/S1600536814014159

Chebout O., Boudraa M., Bouacida S., Merazig H., Boudaren C. Acta Cryst. 2016, E72: 212-214 https://doi.org/10.1107/S2056989016000785

Dolomanov O. V., Bourhis L. J., Gildea R. J., Howard J. A. K., Puschmann H. J. Appl. Cryst. 2009, 42: 339-341 https://doi.org/10.1107/S0021889808042726

Sheldrick G. M. Acta Cryst. 2015, A71: 3-8 https://doi.org/10.1107/S2053273314026370

Sheldrick G. M. Acta Cryst. 2015, C71: 3-8 https://doi.org/10.1107/S2053229614024218

Spackman M. A., Jayatilaka D. CrystEngComm, 2009, 11: 19-32

https://doi: 10.1039/B818330A

McKinnon J. J., Jayatilaka D., Spackman M. A. Chem. Commun. 2007, 3814-3816 https://doi.org/10.1039/B704980C

Tan S. L., Jotani M. M., Tiekink E. R. T. Acta Cryst. 2019, E75: 308-318 https://doi.org/10.1107/S2056989019001129

Wolff S. K., Grimwood D. J., McKinnon J. J., Turner M. J., Jayatilaka D. and Spackman M. A. 2012. Crystal Explorer. University of Western Australia.

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Published

2022-09-01

How to Cite

CHEBOUT, O. .; BOUDRAA, M.; MERAZIG, H. . . CRYSTAL STRUCTURE AND HIRSHFELD ANALYSIS OF (C7H5NS)2SNCL6.2H2O . Journal of Fundamental and Applied Sciences, [S. l.], v. 14, n. 3, p. 567–575, 2022. DOI: 10.4314/jfas.1237. Disponível em: https://jfas.info/index.php/JFAS/article/view/1237. Acesso em: 23 jan. 2025.

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