CRYSTAL STRUCTURE AND HIRSHFELD ANALYSIS OF (C7H5NS)2SNCL6.2H2O

Authors

  • Oussama Chebout Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale (CHEMS), Faculté des Sciences Exactes, Université Constantine-1 25000, Algeria
  • M'hamed Boudraa Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale (CHEMS), Faculté des Sciences Exactes, Université Constantine-1 25000, Algeria
  • Hocine Merazig Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale (CHEMS), Faculté des Sciences Exactes, Université Constantine-1 25000, Algeria

DOI:

https://doi.org/10.4314/jfas.1237

Keywords:

Benzothiazole stannate, hydrogen bonds, single-crystal, X-ray diffraction, Hirshfeld surface.

Abstract

The compound bisbenzothiazolium hexacholoridostannate(II) dihydrate was obtained and structurally characterized by single-crystal X-ray diffraction techniques. The ionic compound crystallizes in the triclinic, space group P-1. The environment of the Sn ion is octahedral slightly deformed. Supramolecular architecture involves C—H…O, C—H…Cl and N—H…O hydrogen bonds and featuring p–p stacking interactions link the molecules into a three-dimensional network. Hirshfeld analysis was performed to show the intermolecular interactions in the crystal structure.  

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References

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Published

2022-09-01

How to Cite

CHEBOUT, O. .; BOUDRAA, M.; MERAZIG, H. . . CRYSTAL STRUCTURE AND HIRSHFELD ANALYSIS OF (C7H5NS)2SNCL6.2H2O . Journal of Fundamental and Applied Sciences, [S. l.], v. 14, n. 3, p. 567–575, 2022. DOI: 10.4314/jfas.1237. Disponível em: https://jfas.info/index.php/JFAS/article/view/1237. Acesso em: 25 sep. 2022.

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