PESTICIDE OCCURRENCE AND DISTRIBUTION IN CULTIVATED SOILS OF THE ARID REGION OF EL-HEJERA, OUARGLA PROVINCE AND CORRELATION WITH SOIL PROPERTIES
DOI:
https://doi.org/10.4314/jfas.v12i1.4Keywords:
pesticides residues, cultivated soils, HPLC, El-Hejera, transformationAbstract
This study deals with the assessment of the most used pesticides by farmers in the Saharan region of Ouargla. Based on collected survey data, sampling of the cultivated soils, physicochemical analysis, solid/liquid extraction and identification by thin layer chromatography and high performance liquid chromatography, the following results were obtained: pesticides used in 2015 are not existing in the extracts, like the case of vapcomic (abamectin 1.8% EC) and Metronate (methomyle 25%), this could be explained by the retention which is the overall result of a set of elementary processes, involving interactions with organic constituents and soil minerals. Also, pesticide residues were found outside their points of application, such as Pulsar and Score 250EC, these phenomena can be explained by the local pedo-climatic conditions and to difference in solubility and chemical nature.
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References
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[31] Hu Q, Wang X and Brusseau ML. Quantitative structure-activity relationships for evaluating the influence of sorbate structure onsorption of organic compounds by soil. Environ. Technol. Chem., 1995, 14(7),1133-1140
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[34] Daoud Y and Halitim A. Irrigation et salinisation au Sahara Algérien. Sécheresse, 1994, 5(3), 151-160
[35] Lucchesi ME, Chemat F and Smadja J. An original solvent free microwave extraction of essential oils from spices. Flavour Frag. J., 2004, 19(2), 134-138
[36] Kalasz H and Bathori M. "Present status and future perspectives of thin layer chromatography." LC-GC Europe, 1997, 10(7), 440-445
[2] Alexander M. Biodegradation of chemicals of environmental concern. Science, 1981, 211 (9), 132-138
[3] Guo L, Nordmark CE, Spurlock FC, Johnson BR, Li L, Marshall Lee J and Goh KS. Characterizing dependence of pesticide load in surface water on precipitation and pesticde use for the Sacramento River watershed. Environ. Sci. Technol., 2004, 38, 3842-3852
[4] Yurtkuran Z and Saygi Y. Assessment of pesticide residues in Karabogaz Lake from KIzIlIrmak Delta, Turkey. B. Environ. Contam Tox., 2013, 91(2), 165-170
[5] Papadakis EN, Tsaboula A, Kotopoulou A, Kintzikoglou K, Vryzas Z, and Papadopoulou-Mourkidou E. Pesticides in the surface waters of Lake Vistonis Basin, Greece: Occurrence and environmental risk assessment. Sci. Total Environ., 2015, 536, 793–802
[6] Gilliom R J. Pesticides in U.S. Streams and Groundwater. Environ. Sci. Technol., 2007, 3409–3414
[7] Beltran J, Hernandez F, Lopez FJ and Morell I. Study of sorption processes of selected pesticides on soils and ceramic porous cups used for soil solution sampling. Int. J. Environ. Analyt. Chem., 2001, 58, 287-303
[8] Gavrilescu M. Fate of pesticides in the environment and in bioremediation. Eng. Life Sci., 2005, 5: 497-526
[9] Beestman GB and Deming JM. Dissipation of acetanilide herbicides from soils. Agronomy J., 1974, 66, 308-311
[10] Fusi P. Adsorption et décomposition catalytique des pesticides sur les minéraux argileux. XXI Congrès du Groupe Français des Pesticides, Nancy 22-23 mai 1991, 31-44
[11] Ristori GG and Fusi P. Adsorption mecanisms and abiotic catalytic transformations of some agrochemicals by clay minerals. In: Envirnmental Impact of soil component interactions, 1995, volume 1: natural and anthropogenic organics. CRCP Inc., 337-343
[12] Fournier JC, Soulas G and Pareth N. Main Microbial Mechanisms of pesticides Degradation in soil. In. Ecotoxicology, 1996, Cha. 4, CRC, Press Lewiss Publisher
[13] Soulas G. Evidence for the existence of different physiological groups in the microbial community responsible for 2,4-D mineralization in soil. Soil Biol. Biochem., 1993, 25, 443-449
[14] Raupach MR, Briggs PR, Ahmad N and Edge VE. Endosulfan transport II: Modellling airborne dispersal and deposition by spray and vapour. J. Env. Quality, 2001, 30(3): 729-740
[15] Asman W, Jorgensen A and Jensen PK. Dry deposition and spray drift of pesticides to nearby water bodies. 2003, 87, 7972-946, Danish Environmental Protection Agency.
[16] Ganzelmeier H and Schmidt K. A German approach on how to measure spray distribution in orchards/vineyards. Proceedings 7th work-shop on Spray Application Techniquesin Fruit Growing, 347–357, Cuneo Italy 2003
[17] Rautmann R. Testing and listing of drift reducing sprayers in Germany. 2002
[18] Aubert G. Méthodes d’analyses des sols. 1978, Ed. C.R.D.P., Marseille, pp 191
[19] Kah M and Brown CD. Prediction of the adsorption of ionizable pesticides in soils. J Agric. Food Chem., 2007, 55, 2312-2322
[20] De Jonge H and De Jonge LW. Influence of pH and solution composition on the sorption of glyphosate and prochloraz to a sandy loam soil. Chemosphere, 1999, 39, 753- 763
[21] Thorstensen CW, Lode O, Eklo M and Christiansen A. Sorption of Bentazone, Dichlorprop, MCPA, and Propiconazole in reference soils from Norway. J. Environ. Qual., 2001, 30, 2046-2052
[22] Boivin A, Cherrier R and Schiavon M. A comparison of five pesticides adsorption and desorption processes in thirteen contrasting field soils. Chemosphere, 2005, 61, 668-676
[23] Barriuso E and Calvet R, Schiavon M, Soulas G. Les pesticides et les polluants organiques des sols: Transformation et dissipation. Etude et Gestion des sols, 1996, 3(4), 279-296.
[24] Coquet Y and Barriuso E. Spatial variability of pesticide adsorption within the topsoil of a small agricultural catchment. Agronomie, 2002, 22, 389-398
[25] Weber J B, Wilkerson G G and Reinhardt CF. Calculating pesticide sorption coefficient (Kd) using selected soil properties. Chemosphere, 2004, 55, 2:157-166
[26] Calvet R, Barriuso E, Bedos P. Benoit P, Charnay MP and Coquet P. Les pesticides dans le sol. Conséquences agronomiques et environnementales. 2005. France agricole, Paris.
[27] Baer U. Comportement des pesticides dans le sol: Evaluation et simulation de la dissipation au champ. Doctoral thesis, 1996, Institut National Agronomique, Paris-Grigno, 155p.
[28] Walker W. 1978. Insecticide persistence in natural seawater as affected by salinity, temperature, and sterility. Environmental Research Laboratory, Office of Research and Development, U.S Enviromental Protection Agency. pp 14-15
[29] Hassett J J, Banwart W L, Wood SG and Means JC. Sorption of a-naphtol: implication concerning the limit of hydrophobic sorption. Soil Sci. Soc. Amer. J., 1981, 45(1), 38-42
[30] Xing B, McGill W B and Dudas MJ. Cross-correlation of polarity curves to predict partition coefficient of nonionic organic contaminants. Environ. Sci. Technol., 1994, 28(11), 1929-1933
[31] Hu Q, Wang X and Brusseau ML. Quantitative structure-activity relationships for evaluating the influence of sorbate structure onsorption of organic compounds by soil. Environ. Technol. Chem., 1995, 14(7),1133-1140
[32] Cornet A. Initiation à l’hydrogéologie Saharienne. Cours ronéoté destiné aux officiers du cours préparatoire aux Affaires Sahariennes. 1964, Service des études scientifiques. Birmandreis, Alger. 108 p
[33] Busson G. Sédimentation, transgression et paléogéographie sur les grandes plateformes du Mésozoïque: l’exemple du Cénomanien- Turonien du NE de la plateforme saharienne et de Berberie. Bull. Soc. Géol., 1971, 701.
[34] Daoud Y and Halitim A. Irrigation et salinisation au Sahara Algérien. Sécheresse, 1994, 5(3), 151-160
[35] Lucchesi ME, Chemat F and Smadja J. An original solvent free microwave extraction of essential oils from spices. Flavour Frag. J., 2004, 19(2), 134-138
[36] Kalasz H and Bathori M. "Present status and future perspectives of thin layer chromatography." LC-GC Europe, 1997, 10(7), 440-445
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Published
2019-11-06
How to Cite
ALOUI, N.; OULED-HADDAR, H.; BISSATI, S.; KRAIMAT, M.; OMEIRI, N. PESTICIDE OCCURRENCE AND DISTRIBUTION IN CULTIVATED SOILS OF THE ARID REGION OF EL-HEJERA, OUARGLA PROVINCE AND CORRELATION WITH SOIL PROPERTIES. Journal of Fundamental and Applied Sciences, [S. l.], v. 12, n. 1, p. 35–48, 2019. DOI: 10.4314/jfas.v12i1.4. Disponível em: https://jfas.info/index.php/JFAS/article/view/461. Acesso em: 30 jan. 2025.
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