SYNTHESIS AND CHARACTERIZATION OF DIMETHACRYLATE MACROMONOMER USING MAGHNITE-H+ AS AN ECO-FRIENDLY CATALYST
DOI:
https://doi.org/10.4314/jfas.v12i2.19Keywords:
Maghnite-H ; glycidyl methacrylate; maleic anhydride; bis-methacrylate macromonomer.Abstract
The dimethacrylate macromonomer named bis (2-hydroxy-3-(méthacryloyloxy) propyl) fumarate (HMPF), was synthesized by ring opening reaction of epoxide function of glycidyl methacrylate (GMA) with maleic anhydride (MA) in presence of Maghnite-H+ as a catalyst at room temperature and at free solvent. The Maghnite-H+ is a proton exchanged montmorillonite clay it is an Algerian clay activated by sulfuric acid 0,23M. The HMPF was characterized by FT-IR, 1H NMR and 13C NMR spectroscopic techniques. A kinetic study was carried out to determine the amount of the catalyst (5, 10, 20 and 30%) which will give a better yield of the synthesis reaction. The yield of the reaction was 62.23% for a quantity of Maghnite-H+ (20% relative to the monomer) and for a reaction time of 72h.
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References
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[2] Assumption H. J., Mathias L. J., Polym. 2003, 44, 5131–5136
doi: 10.1016/S0032-3861(03)00530-5
[3] He S, Yaszemski M.J, Yasko A.W, Engel P.S, Mikos A.G. Injectable biodegradable polymer composites based on poly (propylene fumarate) crosslinked with poly(ethylene glycol)-dimethacrylate. Biomat. 2000, 21, 2389-2394
[4] Walters N.J., Xia W., Salih V., Ashley P.F., Young A.M., Dent. Mat. 2016, 32(2), 264-277.
doi:10.1016/j.dental.2015.11.017
[5] Amirouche K.A, Mouzali M, Watts D.C. Shrinkage strain – Rates study of dental composites based on (BisGMA/TEGDMA) monomers. Arab. J. Chem. 2017, 10, S190–S195
[6] Tarley C.R., Corazza M.Z., Somera B.F., Segatelli G.F., J. Coll. Inte. Sc. 2015, 450, 254–263
doi: 10.1016/j.jcis.2015.02.074
[7] Lin H, Kai T., Freeman B.D, Kalakkunnath S., Kalika D.S., Macro. 2005, 38 (20), 8381-8393
doi: 10.1021/ma0510136
[8] Hung C.Y, Hsieh S.J, Wang C.C, Chen C.Y. Structural characterization and thermal behavior of dentritic-linear PGMA-HPAM-r-PS copolymers in a self-assembled microporous matrix. Polym. Degr. Stab., 2013, 98, 1196-1204
[9] Demir K.D, Kiskan B, Aydogan B, Yagci Y. Thermally curable main-chain benzoxazine prepolymers via polycondensation route. Rea. Func. Polym., 2013, 73 (2), 346–359
[10] Arslantas A., Sinirlioglu D., Eren F., Muftuoglu A.E., Bozkurt A., J. Polym. Res. 2014, 21:437
doi: 10.1007/s10965-014-0437-0
[11] Abu-Saied M.A., Fontananova E., Drioli E., Mohy Eldin M.S., J. Polym. Res. 2013, 20:187
doi: 10. 1007/s10965-013-0187-4
[12] Bagheri M., Motirasoul F., J. Polym. Res. 2013, 20:59
doi: 10. 1007/s10965-012-0059-3
[13] Trakulsujaritchok T., Noiphom N., Tangtreamjitmun N., Saeeng R., J. Mater. Sci. 2011, 46:5350–5362
doi:10. 1007/s10853-011-5473-0
[14] Oscar J.O.P., Jose C., Dutra F., Paulo H.S.P., Marcos L.D., Ion. 2015, 21:755–764
doi: 10.1007/s11581-014-1212-2
[15] Xiao L., Li Z., Dong J., Liu L., Shang L., Zhang X., Zhang H., Ao Y., Dong A., Coll. Poly. Sci. 2015, 293:2807–2813.
doi:10.1007/s00396-015-3652-2
[16] Souli L, Harrane A, Meghabar R, Lahrech M.B, Belbachir M. Ring opening polymerization of glycidyl methacrylate by Maghnite-H+ as solide catalyst. Bio. Res. App. Chem. 2011, I (5), 196-202
[17] Souli L, Meghabar R, Djemoui A, Lahrech MB, Belbachir M. Water-soluble poly (HMBC-co-AM) prepared using tetrafunctional methacrylate macromonomer. J. Chem. Phar. Res. 2015, 7(10), 108-115
[18] Lahouaria M., Belbachir M., Bull. Chem. Rea. Eng. Cat. 2016, 11 (2), 151-160. doi:10.9767/bcrec.11.2.541.151-160
[19] Rahmouni A, Belbachir M., Bull. Chem. Rea. Eng. Cat. 2016, 11 (2), 170-175. doi:10.9767/bcrec.11.2.543.170-175
[20] Kherroub D.E, Belbachir M, Lamouri S., Bul. Chem. Reac. Eng. Cat. 2014, 9 (1):74-80
doi.org/10.9767/bcrec.9.1.5555.74-80
[21] Belbachir M, Bensaoula A. Composition and method for catalysis using bentonites. 2001, US6274527, U.S. Patent.
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Published
2020-04-27
How to Cite
SOULI, L.; MEGHABAR, R.; LAHRECH, M. B. SYNTHESIS AND CHARACTERIZATION OF DIMETHACRYLATE MACROMONOMER USING MAGHNITE-H+ AS AN ECO-FRIENDLY CATALYST. Journal of Fundamental and Applied Sciences, [S. l.], v. 12, n. 2, p. 814–824, 2020. DOI: 10.4314/jfas.v12i2.19. Disponível em: https://jfas.info/index.php/JFAS/article/view/87. Acesso em: 30 jan. 2025.
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