INHIBITING ALUMINIUM ACID CORROSION USING LEAVES EXTRACT OF GUIERA SENEGALENSIS
DOI:
https://doi.org/10.4314/jfas.v13i2.1Keywords:
Inhibition efficiency, Thermodynmaics, Weight loss, FT-IR, Asdorption isothermsAbstract
The effects of Guiera senegalensis leaves extract as a potential green corrosion inhibitor for Aluminum (Al) in HCl acid solution was investigated using weight loss, LPR, FT-IR, and scanning electron microscope techniques at varying experimental conditions. The result indicates that the percentage inhibition efficiency increases with increase in concentration of the inhibitor and decreased with increase in temperature and immersion period. SEM images showed that the Al metal is protected by the inhibitor molecules, while FT-IR spectra indicates the mechanism of physical adsorption of inhibitors onto Al surface. LPR result showed that the inhibition efficiency of the inhibitor was moderate and act as mixed-type inhibitor. The data obtained from the thermodynamic parameters were fitted into various adsorption isotherms, Freundlich adsorption isotherm was observed to be the best fitted isotherm.
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References
[1] Hari K. S. and Karthikeyan S. Torsemide and furosemide as green inhibitors for the corrosion of mild steel in hydrochloric acid medium. Industrial & Engineering Chemistry Research, 2013, 52(22), 7457-7469.
[2] Bashir, S., Lgaz, H., Chung, I.-M., & Kumar, A. Effective green corrosion inhibition of aluminium using analgin in acidic medium: an experimental and theoretical study. Chemical Engineering Communications, 2020, 1-10.
[3] Muralidharan, S., Chandrasekar, R. and Iyer, S.V.K. Effect of piperidones on hydrogen permeation and inhibition of mild steel in acidic solutions. Proccurement of Indian Academy of Science 2000, 112(2): 127-136.
[4] Rani B.E.A, & Basu, B.B.J. Green Inhibitors for Corrosion Protection of Metals and Alloys: An Overview. International Journal of Corrosion. 2012, doi: 10.1155/2012/380217.
[5] Ladha D.G, Wadhwani P.M, Lone M.Y, Jha P.C, & Shah N.K. Evaluation of Fennel Seed Extract as a Green Corrosion Inhibitor for Pure Aluminum in Hydrochloric Acid: An Experimental and Computational Approach. Analytical & Bioanalytical Electrochemistry, 2015, 7(1), 59-74.
[6] Nathiya, R., Perumal, S., Murugesan, V., & Raj, V. Evaluation of extracts of Borassus flabellifer dust as green inhibitors for aluminium corrosion in acidic media. Materials Science in Semiconductor Processing, 2019, 104, 104674.
[7] Abd El Rehim S.S, Hassan H.H., & Amin, M.A. The corrosion inhibition study of sodium dodecyl benzene sulphonate to aluminium and its alloys in 1.0 M HCl solution. Materials Chemistry and Physics, 2002, 78, 337-348.
[8] Anbarasi, C. M., & Divya, G. A Green Approach to Corrosion Inhibition of Aluminium in Acid Medium Using Azwain Seed Extract. Paper presented at the 6th International Conference of Materials Processing and Characterization (ICMPC 2016).
[9] Mukherjee, D., Berchman, J., Rajsekkar, A., Sundarsanan, N., Mahalingam, R., Maruthamuthu, S., Karaikudi, D. Plant‐based alkaloids inhibit corrosion of marine alloys. Anti-Corrosion Methods and Materials. 1997.
[10] Sangeetha, M., Rajendran, S., Muthumegala, T., & Krishnaveni, A. Green corrosion inhibitors-an overview. Zastita Materijala, 2011, 52(1), 3-19.
[11] Abdel-Gaber, A., Abd-El-Nabey, B., Sidahmed, I., El-Zayady, A., & Saadawy, M. Inhibitive action of some plant extracts on the corrosion of steel in acidic media. Corrosion Science, 2006, 48(9), 2765-2779.
[12] Rathi P, Trikha S, & S., K. Plant extracts as green corrosion inhibitors in various corrosive media- a review. World journal of pharmacy and pharmaceutical sciences, 2017, 6(4), 482-514.
[13] Silva, O., Serrano, R., and Gomes, E. T. Botanical characterization of Guiera senegalensis leaves. Microscopy and Microanalysis, 2008, 14(5), 398-404.
[14] Berhaut, J. Flore illustrée du Sénégal, Gouvernement du Sénégal, Ministère du développement rural, Direction des. 1988 (Vol. 9).
[15] Yıldız, R. An electrochemical and theoretical evaluation of 4, 6-diamino-2-pyrimidinethiol as a corrosion inhibitor for mild steel in HCl solutions. Corrosion Science, 2015, 90, 544-553.
[16] Umoren S, Obot I.B, Gasem Z, and Odewunmi N.A. Experimental and Theoretical Studies of Red Apple Fruit Extract as Green Corrosion Inhibitor for Mild Steel in HCl Solution. Journal of Dispersion Science and Technology. 2015, doi: 10.1080/01932691.2014.922887
[17] Bereket, G., Ög˘retir, C. and Yurt, A. Quantum mechanical calculations on some 4- methyl-5-substituted imidazole derivatives as acidic corrosion inhibitor for zinc. Journal of Molecular Structure (THEOCHEM), 2001, 571:139–145.
[18] Obot, I.B., and Obi-Egbedi. N.O. An interesting and efficient green corrosion inhibitor for aluminium from extracts of Chlomolaena odorata L. in acidic solution. Journal of Electrochemistry, 2010, 40 (11), 1977-1984.
[19] Parvez K. M, Alam P, A.H, A., Al-Dosari, M. S., Alhowiriny T. A, & Alqsoumi, I.S. Analysis of antioxidative and antiviral biomarkers b-amyrin, b-sitosterol, lupeol, ursolic acid in Guiera senegalensis leaves extract by validated HPTLC methods. Saudi Pharmaceutical Journal. 2018.
[20] Somboro, A. A., Patel, K., Diallo, D., Sidibe, L., Chalchat, J. C., Figueredo, G., Chalard, P. An ethnobotanical and phytochemical study of the African medicinal plant Guiera senegalensis JF Gmel. Journal of Medicinal Plants Research, 2011, 5(9), 1639-1651.
[21] Tiwari Prishant, Bimlesh Kumar, Mandeep Kaur, Gurpreet Kaur and Harleen Kaur Phytochemical screening and extraction: A Review. International pharmaceutica sciencia, 2011, 1(1): 98-106.
[22] Al Shafei N.K, Elshafie A.E, & Nour, A. Antitoxic, Antifungal and Phytochemical Analysis of Medicinal Compounds of Guiera senegalensis Leaves in Sudan. J. Plant Biochemistry & Physiology, 2016, 4(2), 166.
[23] Hamad M.S, Elsafi H, Saeed A, Fadul E, & R.H., A. A Review on the Taxonomy, Ethnobotany, Phytochemistry and Pharmacology of Guriea senegalensis J. F. Gmel. (Combretaceae). Medicinal & Aromatic Plants, 2017, 6(4). doi: 10.4172/2167-0412.1000296.
[24] Olasehinde, E., Ogunjobi, J., Akinlosotu, O., & Omogbehin, S. Investigation of the Inhibitive Properties of Alchornea laxiflora leaves on the Corrosion of Mild Steel in HCl: Thermodynamics and Kinetic Study. Journal of American Science, 2015, 11(1), 32-39.
[25] Stern, M., & Geary, A. L. Electrochemical polarization: I. A theoretical analysis of the shape of polarization curves. Journal of the Electrochemical Society, 1957, 104(1), 56.
[26] Ropital, F. Environmental degradation in hydrocarbon fuel processing plant: issues and mitigation Advances in Clean Hydrocarbon Fuel Processing Elsevier. 2011, 437-462.
[27] Govindasamy, R., & Ayappan, S. Study of Corrosion inhibition properties of novel Semicarbazones on mild steel in acidic solutions. Journal of the Chilean Chemical Society, 2015, 60(1), 2786-2798.
[28] Fiot J, Sanon S, Azas N, Mahioua V, Jansen O, Angenot L, E., O. Phytochemical and pharmacological study of roots and leaves of Guiera senegalensis J.F. Gmel (Combretaceae). Journal of Ethnopharmacology, 2006, 106, 173-178.
[29] Fares, M. M., Maayta, A., & Al-Qudah, M. M. Pectin as promising green corrosion inhibitor of aluminum in hydrochloric acid solution. Corrosion Science, 2012 60, 112-117.
[30] Krishnaveni, K., & Ravichandran, J. Effect of aqueous extract of leaves of Morinda tinctoria on corrosion inhibition of aluminium surface in HCl medium. Transactions of Nonferrous Metals Society of China, 2014, 24(8), 2704-2712.
[31] Udom, G. I., Cookey, G. A. and Abia, A. A. (2017). The Effect of Acanthus montanusLeaves Extract on Corrosion of Aluminium in Hydrochloric Acid Medium. Journal of Applied Science and Technology. 2017, 25(2): 1-11.
[32] Oguzie, E.E., Onuchukwu, A.I., Okafor, P.C. and Ebenso, E.E. Corrosion inhibition and adsorption behavior of Occimum basiclicum extract on aluminum. Pigment and Resin technology, 2006, 35(2):63-70.
[33] Oguzie, E. E., Adindu, C. B., Enenebeaku, C. K., Ogukwe, C. E., Chidiebere, M. A., & Oguzie, L. L. Natural products for materials protection: Mechanism of corrosion inhibition of mild steel by acid extracts of Piper guineense. Journal of Physical Chemistry, 2012, doi: 10.1021/jp300791s.
[34] Rao Padmalatha and PrabhuDeepa Corrosion inhibition of 6063 aluminium alloy by coriandrumsatirum L. seed extract in phosphoric acid medium. Journal of material and environmental science, 2013, 4: 732-743.
[35] Eddy, N. O., Ameh, P. O., & Essien, N. B. Experimental and computational chemistry studies on the inhibition of aluminium and mild steel in 0.1 M HCl by 3-nitrobenzoic acid. Journal of Taibah University for Science, 2018, 12(5), 545-556.
[36] Ating E.I, Umoren S.A, Udousoro I.I, Ebenso E.E, & A.P., U. Leaves extract of Ananas sativum as green corrosion inhibitor for aluminium in hydrochloric acid solutions. Green Chemistry Letters and Reviews, 2010, 3(2), 61-68, doi: 10.1080/17518250903505253.
[37] Loto, C. A. Inhibition effect of tea (Camellia Sinensis) extract on the corrosion of mild steel in dilute sulphuric acid. Journal of Materials and Environmental Science, 2011, 2: 335–344.
[38] Awe F.E, Idris S.O, Abdulwahab M, & Oguzie, E.E. Theoretical and experimental inhibitive properties of mild steel in HCl by ethanolic extract of Boscia senegalensis. Cogent Chemistry. 2015, 1(1) doi: org/10.1080/23312009.2015.1112676.
[39] Oguzie, E. E. Corrosion inhibitive effect and adsorption behaviour of Hibiscus Sabdariffa extract on mild steel in acidic media. Portugaliae Electrochimical Acta, 2008, 26: 303-314.
[40] Fadare O. O., Okonkwo A. E. and Olasehinde E. F. Assessment of anti-corrosion potentials of extract of Ficus asperifoliamiq (morceae) on mild steel in acidic medium. African journal of pure and applied chemistry, 2016, 10(1): 8-22.
[41] Zhao Qian, Tiantian Tang, Peilin Dang, Zhiyi Zhang and Fang Wang. The corrosion inhibition effect of Triazinedithiol inhibitors for Aluminium Alloy in a 1M HCl solution. Metals, 2017, 7(44), doi: 10.3390/met7020044.
[42] Okafor, P.C. and Ebenso, E.E. Inhibitive action of Carica papaya extracts on the corrosion of mild steel in acidic media and their adsorption characteristics. Pigment and Resin Technology 2007, 36(3):134-140.
[2] Bashir, S., Lgaz, H., Chung, I.-M., & Kumar, A. Effective green corrosion inhibition of aluminium using analgin in acidic medium: an experimental and theoretical study. Chemical Engineering Communications, 2020, 1-10.
[3] Muralidharan, S., Chandrasekar, R. and Iyer, S.V.K. Effect of piperidones on hydrogen permeation and inhibition of mild steel in acidic solutions. Proccurement of Indian Academy of Science 2000, 112(2): 127-136.
[4] Rani B.E.A, & Basu, B.B.J. Green Inhibitors for Corrosion Protection of Metals and Alloys: An Overview. International Journal of Corrosion. 2012, doi: 10.1155/2012/380217.
[5] Ladha D.G, Wadhwani P.M, Lone M.Y, Jha P.C, & Shah N.K. Evaluation of Fennel Seed Extract as a Green Corrosion Inhibitor for Pure Aluminum in Hydrochloric Acid: An Experimental and Computational Approach. Analytical & Bioanalytical Electrochemistry, 2015, 7(1), 59-74.
[6] Nathiya, R., Perumal, S., Murugesan, V., & Raj, V. Evaluation of extracts of Borassus flabellifer dust as green inhibitors for aluminium corrosion in acidic media. Materials Science in Semiconductor Processing, 2019, 104, 104674.
[7] Abd El Rehim S.S, Hassan H.H., & Amin, M.A. The corrosion inhibition study of sodium dodecyl benzene sulphonate to aluminium and its alloys in 1.0 M HCl solution. Materials Chemistry and Physics, 2002, 78, 337-348.
[8] Anbarasi, C. M., & Divya, G. A Green Approach to Corrosion Inhibition of Aluminium in Acid Medium Using Azwain Seed Extract. Paper presented at the 6th International Conference of Materials Processing and Characterization (ICMPC 2016).
[9] Mukherjee, D., Berchman, J., Rajsekkar, A., Sundarsanan, N., Mahalingam, R., Maruthamuthu, S., Karaikudi, D. Plant‐based alkaloids inhibit corrosion of marine alloys. Anti-Corrosion Methods and Materials. 1997.
[10] Sangeetha, M., Rajendran, S., Muthumegala, T., & Krishnaveni, A. Green corrosion inhibitors-an overview. Zastita Materijala, 2011, 52(1), 3-19.
[11] Abdel-Gaber, A., Abd-El-Nabey, B., Sidahmed, I., El-Zayady, A., & Saadawy, M. Inhibitive action of some plant extracts on the corrosion of steel in acidic media. Corrosion Science, 2006, 48(9), 2765-2779.
[12] Rathi P, Trikha S, & S., K. Plant extracts as green corrosion inhibitors in various corrosive media- a review. World journal of pharmacy and pharmaceutical sciences, 2017, 6(4), 482-514.
[13] Silva, O., Serrano, R., and Gomes, E. T. Botanical characterization of Guiera senegalensis leaves. Microscopy and Microanalysis, 2008, 14(5), 398-404.
[14] Berhaut, J. Flore illustrée du Sénégal, Gouvernement du Sénégal, Ministère du développement rural, Direction des. 1988 (Vol. 9).
[15] Yıldız, R. An electrochemical and theoretical evaluation of 4, 6-diamino-2-pyrimidinethiol as a corrosion inhibitor for mild steel in HCl solutions. Corrosion Science, 2015, 90, 544-553.
[16] Umoren S, Obot I.B, Gasem Z, and Odewunmi N.A. Experimental and Theoretical Studies of Red Apple Fruit Extract as Green Corrosion Inhibitor for Mild Steel in HCl Solution. Journal of Dispersion Science and Technology. 2015, doi: 10.1080/01932691.2014.922887
[17] Bereket, G., Ög˘retir, C. and Yurt, A. Quantum mechanical calculations on some 4- methyl-5-substituted imidazole derivatives as acidic corrosion inhibitor for zinc. Journal of Molecular Structure (THEOCHEM), 2001, 571:139–145.
[18] Obot, I.B., and Obi-Egbedi. N.O. An interesting and efficient green corrosion inhibitor for aluminium from extracts of Chlomolaena odorata L. in acidic solution. Journal of Electrochemistry, 2010, 40 (11), 1977-1984.
[19] Parvez K. M, Alam P, A.H, A., Al-Dosari, M. S., Alhowiriny T. A, & Alqsoumi, I.S. Analysis of antioxidative and antiviral biomarkers b-amyrin, b-sitosterol, lupeol, ursolic acid in Guiera senegalensis leaves extract by validated HPTLC methods. Saudi Pharmaceutical Journal. 2018.
[20] Somboro, A. A., Patel, K., Diallo, D., Sidibe, L., Chalchat, J. C., Figueredo, G., Chalard, P. An ethnobotanical and phytochemical study of the African medicinal plant Guiera senegalensis JF Gmel. Journal of Medicinal Plants Research, 2011, 5(9), 1639-1651.
[21] Tiwari Prishant, Bimlesh Kumar, Mandeep Kaur, Gurpreet Kaur and Harleen Kaur Phytochemical screening and extraction: A Review. International pharmaceutica sciencia, 2011, 1(1): 98-106.
[22] Al Shafei N.K, Elshafie A.E, & Nour, A. Antitoxic, Antifungal and Phytochemical Analysis of Medicinal Compounds of Guiera senegalensis Leaves in Sudan. J. Plant Biochemistry & Physiology, 2016, 4(2), 166.
[23] Hamad M.S, Elsafi H, Saeed A, Fadul E, & R.H., A. A Review on the Taxonomy, Ethnobotany, Phytochemistry and Pharmacology of Guriea senegalensis J. F. Gmel. (Combretaceae). Medicinal & Aromatic Plants, 2017, 6(4). doi: 10.4172/2167-0412.1000296.
[24] Olasehinde, E., Ogunjobi, J., Akinlosotu, O., & Omogbehin, S. Investigation of the Inhibitive Properties of Alchornea laxiflora leaves on the Corrosion of Mild Steel in HCl: Thermodynamics and Kinetic Study. Journal of American Science, 2015, 11(1), 32-39.
[25] Stern, M., & Geary, A. L. Electrochemical polarization: I. A theoretical analysis of the shape of polarization curves. Journal of the Electrochemical Society, 1957, 104(1), 56.
[26] Ropital, F. Environmental degradation in hydrocarbon fuel processing plant: issues and mitigation Advances in Clean Hydrocarbon Fuel Processing Elsevier. 2011, 437-462.
[27] Govindasamy, R., & Ayappan, S. Study of Corrosion inhibition properties of novel Semicarbazones on mild steel in acidic solutions. Journal of the Chilean Chemical Society, 2015, 60(1), 2786-2798.
[28] Fiot J, Sanon S, Azas N, Mahioua V, Jansen O, Angenot L, E., O. Phytochemical and pharmacological study of roots and leaves of Guiera senegalensis J.F. Gmel (Combretaceae). Journal of Ethnopharmacology, 2006, 106, 173-178.
[29] Fares, M. M., Maayta, A., & Al-Qudah, M. M. Pectin as promising green corrosion inhibitor of aluminum in hydrochloric acid solution. Corrosion Science, 2012 60, 112-117.
[30] Krishnaveni, K., & Ravichandran, J. Effect of aqueous extract of leaves of Morinda tinctoria on corrosion inhibition of aluminium surface in HCl medium. Transactions of Nonferrous Metals Society of China, 2014, 24(8), 2704-2712.
[31] Udom, G. I., Cookey, G. A. and Abia, A. A. (2017). The Effect of Acanthus montanusLeaves Extract on Corrosion of Aluminium in Hydrochloric Acid Medium. Journal of Applied Science and Technology. 2017, 25(2): 1-11.
[32] Oguzie, E.E., Onuchukwu, A.I., Okafor, P.C. and Ebenso, E.E. Corrosion inhibition and adsorption behavior of Occimum basiclicum extract on aluminum. Pigment and Resin technology, 2006, 35(2):63-70.
[33] Oguzie, E. E., Adindu, C. B., Enenebeaku, C. K., Ogukwe, C. E., Chidiebere, M. A., & Oguzie, L. L. Natural products for materials protection: Mechanism of corrosion inhibition of mild steel by acid extracts of Piper guineense. Journal of Physical Chemistry, 2012, doi: 10.1021/jp300791s.
[34] Rao Padmalatha and PrabhuDeepa Corrosion inhibition of 6063 aluminium alloy by coriandrumsatirum L. seed extract in phosphoric acid medium. Journal of material and environmental science, 2013, 4: 732-743.
[35] Eddy, N. O., Ameh, P. O., & Essien, N. B. Experimental and computational chemistry studies on the inhibition of aluminium and mild steel in 0.1 M HCl by 3-nitrobenzoic acid. Journal of Taibah University for Science, 2018, 12(5), 545-556.
[36] Ating E.I, Umoren S.A, Udousoro I.I, Ebenso E.E, & A.P., U. Leaves extract of Ananas sativum as green corrosion inhibitor for aluminium in hydrochloric acid solutions. Green Chemistry Letters and Reviews, 2010, 3(2), 61-68, doi: 10.1080/17518250903505253.
[37] Loto, C. A. Inhibition effect of tea (Camellia Sinensis) extract on the corrosion of mild steel in dilute sulphuric acid. Journal of Materials and Environmental Science, 2011, 2: 335–344.
[38] Awe F.E, Idris S.O, Abdulwahab M, & Oguzie, E.E. Theoretical and experimental inhibitive properties of mild steel in HCl by ethanolic extract of Boscia senegalensis. Cogent Chemistry. 2015, 1(1) doi: org/10.1080/23312009.2015.1112676.
[39] Oguzie, E. E. Corrosion inhibitive effect and adsorption behaviour of Hibiscus Sabdariffa extract on mild steel in acidic media. Portugaliae Electrochimical Acta, 2008, 26: 303-314.
[40] Fadare O. O., Okonkwo A. E. and Olasehinde E. F. Assessment of anti-corrosion potentials of extract of Ficus asperifoliamiq (morceae) on mild steel in acidic medium. African journal of pure and applied chemistry, 2016, 10(1): 8-22.
[41] Zhao Qian, Tiantian Tang, Peilin Dang, Zhiyi Zhang and Fang Wang. The corrosion inhibition effect of Triazinedithiol inhibitors for Aluminium Alloy in a 1M HCl solution. Metals, 2017, 7(44), doi: 10.3390/met7020044.
[42] Okafor, P.C. and Ebenso, E.E. Inhibitive action of Carica papaya extracts on the corrosion of mild steel in acidic media and their adsorption characteristics. Pigment and Resin Technology 2007, 36(3):134-140.
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Published
2020-12-05
How to Cite
AYUBA, A. M.; ABUBAKAR, M. INHIBITING ALUMINIUM ACID CORROSION USING LEAVES EXTRACT OF GUIERA SENEGALENSIS. Journal of Fundamental and Applied Sciences, [S. l.], v. 13, n. 2, p. 634–656, 2020. DOI: 10.4314/jfas.v13i2.1. Disponível em: https://jfas.info/index.php/JFAS/article/view/982. Acesso em: 30 jan. 2025.
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