STRUCTURAL AND ELECTROCHEMICAL PROPERTIES OF Fe-DOPED NiAl2O4 OXIDE
DOI:
https://doi.org/10.4314/jfas.v11i1.15Keywords:
Spinel oxide, Sol-gel, Powder diffraction, Thermal analysis, Oxygen evolution reaction.Abstract
A new spinel solid solution system of Ni1-xFexAl2O4 (0.0 ≤ x ≤ 0.5) was synthesized through sol-gel method. The effect of Fe doping on the nickel aluminate prepared was investigated. The synthesized powders were characterized by means of X-ray diffraction, thermogravimetric and differential thermal analysis, fourier transform infrared spectroscopy, scanning electron microscopy and electrochemical measurements. From the preceding analysis, it can be shown that compounds show a single spinel phase in the temperature range 650-1000°C and the solubility of iron in the NiAl2O4 structure was limited to samples with the iron content x < 0.6. The electrochemical measurements indicate that the catalytic activity is strongly influenced by iron doping. The highest electrode performance is achieved with Ni0.7Fe0.3Al2O4 (i=86.84 mA/cm2) which is ~ 27 times greater than that of NiAl2O4 ( i=3.22 mA/cm2) at E= +0.8V. After one hundred cycles, the stability of the doped electrode with 30% of iron is much better than the undoped electrode.
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[3] Michel CR, Sensors Actuators B Chem. 147, 2010, 635- 641, doi.org/10.1016/j.snb.2010.04.013
[4] Michel CR, Rivera J, Martinez AH, Santana-Aranda M, J. Electrochem. Soc.155, 2008, 263-269, doi: 10.1149/1.2956971.
[5] Cavalcante PMT, Dondi M, Guarini G, Raimondo M, Baldi G, Dye. Pigment 80, 2009, 226- 232, doi.org/10.1016/j.dyepig.2008.07.004.
[6] Lorenzelli V, Escribano VS, Guidetti R, J. Catal. 131, 1991,167-177, doi.org/10.1016/0021-9517(91)90333-Y
[7] Dussault L, Dupin J-C, Guimon C, Monthioux M, Latorre N, Ubieto T, Romeo E, Royo C, Monzon A, J. Catal. 251, 2007 223-232, doi.org/10.1016/j.jcat.2007.06.022
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[10] Cesteros Y, Salagre P, Medina F, Sueiras J.E, Appl. Catal. B Environ. 25, 2000, 213-227, doi.org/10.1016/S0926-3373(99)00133-2
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[14] Souza LKC, Zamian JR, Filho GNR, Soledade LEB, Santos IMG, Souza AG, Scheller T, Angélica RS, Costa CEF, Dye. Pigm. 81, 2009, 187- 192, doi.org/10.1016/j.dyepig.2008.09.017
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[16] Han YS, Li JB; Ning XS, Yang XZ, Chi B, Mater. Sci. Eng. A 369, 2004, 241-244, doi.org/10.1016/j.msea.2003.11.026
[17] Nazemi MK, Sheibani S, Rashchi F, Gonzalez-DelaCruz VM, Caballero A, Adv. Powder Technol. 23, 2012, 833-838, doi.org/10.1016/j.apt.2011.11.004
[18] Peelamedu RD, Roy R, Agrawal DK, Mater. Lett. 55, 2002, 234-240, doi.org/10.1016/S0167-577X(01)00653-X
[19] Han YS, Li JB, Ning XS, Chi B, J.Am. Ceram. Soc. 88, 2005, 3455-3457, doi.org/10.1016/S0167-577X(01)00653-X
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[23] Li Z, Wang Y, Liu J, Chen G, Li Y, Zhou C, Int. J. Hydrogen Energy 34, 2009, 147-152, doi.org/10.1016/j.ijhydene.2008.10.027
[24] Arean CO, Vinuela JSD, J. Solid State Chem. 60, 1985, 1-5, doi.org/10.1016/0022-4596(85)90156-2
[25] Arean CO, Martinez MLR, Arjona AM, Mater. Chem. Phys. 8, 1983, 443-450, doi.org/10.1016/0254-0584(83)90064-0
[26] Aupretre F, Descorme C, Duprez D, Casanave D, Uzio D, J. Catal. 233, 2005, 464-477, doi.org/10.1016/j.jcat.2005.05.007
[27] Augustin CO, Hema K, Berchmans LJ, Kalai Selvan R, Saraswathi R, Phys. Status Solidi 202, 2005, 1017-1024, doi.org/10.1002/pssa.200420027
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[29] Landon J, Demeter E, Inoglu N, Keturakis C, Wachs IE, Vasic R, ACS Catal. 2, 2012, 1793-1801, doi: 10.1021/cs3002644
[30] Godinho MI, Catarino MA, Silva Pereira MI, Mendonça MH, Costa FM, Electrochim. Acta 47, 2002, 4307-4314, doi.org/10.1016/S0013-4686(02)00434-6
[31] Singh RN, Singh JP, Lal B, Thomas MJK, Bera S, Electrochim. Acta 51, 2006, 5515-5523, doi.org/10.1016/j.electacta.2006.02.028
[32] Rida K, Pena MA, Sastre E, Martinez-Arias A, J. Rare Earths 30, 2012, 210-216, doi.org/10.1016/S1002-0721(12)60025-8
[33] Devi PS, Rao MS, J. Anal. Appl. Pyrolysis 22, 1992, 187-195, doi.org/10.1016/0165-2370(92)85012-A
[34] Wang H, Zhu Y, Liu P, Yao W, J. Mater. Sci. 38, 2003, 1939-1943, doi.org/10.1023/A:1023504514207
[35] Marciuš M, Ristić M, Ivanda M, Musić S, J. Alloys Compd. 541, 2012, 238-243, doi.org/10.1016/j.jallcom.2012.07.021
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[40] Anchieta CG, Tochetto L, Madalosso HB, Sulkovski RD, Serpa C, Mazutti MA,
Almeida A.R.F, Gündel A, Foletto E.L, Ceramica 61, 2015, 477-481, doi.org/10.1590/0366-69132015613601925
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[42] Becheri A, Dürr M, Nostro PL, Baglioni P, J. Nanoparticle Res. 10, 2008, 679-689, doi.org/10.1007/s11051-007-9318-3
[43] Jung GB, Huang TJ, Huang MH, Chang CL, J. Mater. Sci. 36, 2001, 5839-5844, doi.org/10.1023/A:1012964307388
[44] Garcia FAC, Silva JCM, Macedo JL, Dias JA, Dias SCL, Geraldo Filho N.R, Microporous Mesoporous Mater. 113, 2008, 562-574, doi.org/10.1016/j.micromeso.2007.12.017
[45] Li LF, Selloni A, ACS Catal. 4, 2014, 1148-1153, DOI: 10.1021/cs401245q
[46] Xiao C, Lu X, Zhao C, Chem. Commun. 50, 2014, 10122-10125, doi: 10.1039/C4CC04922E
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[48] Friebel D, Louie M. W., Bajdich M, Sanwald K. E., Cai Y, Wise A. M., Cheng M.J., Sokaras D., Weng T.C., Alonso-Mori R, Davis R.C., Bargar J.R., Nørskov J.K., Nilsson A., Bell A.T., J. Am. Chem. Soc. 137, 2015, 1305−1313, doi: 10.1021/ja511559d.
[49] Qi J, Zhang W, Xiang R, Liu K, Wang HY, Chen M, Han Y, Cao R, Adv.Sci. 2, 2015, 1500199-1500206, doi: 10.1002/advs.201500199.
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Published
2018-12-10
How to Cite
TIBERMACINE, W.; OMARI, M. STRUCTURAL AND ELECTROCHEMICAL PROPERTIES OF Fe-DOPED NiAl2O4 OXIDE. Journal of Fundamental and Applied Sciences, [S. l.], v. 11, n. 1, p. 227–244, 2018. DOI: 10.4314/jfas.v11i1.15. Disponível em: https://jfas.info/index.php/JFAS/article/view/117. Acesso em: 29 jan. 2025.
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