• Djamel Eddine Hamza Laboratoire de Chimie, Ingénierie Moléculaire et Nanostructures, Université de Sétif, Algeria
  • Leila LAMIRI Research Center in Industrial Technologies CRTI, P.O. Box 64, Cheraga 16014, Algiers, Algeria
  • Assia Tounsi Laboratoire d’Electrochimie et Matériaux, Département de Génie des Procédés, Faculté de Technologie, Université Ferhat Abbas Sétif, Algérie
  • Amor Aziz Laboratoire de Chimie, Ingénierie Moléculaire et Nanostructures, Université de Sétif, Algeria
  • Mohammad Alam Saeed Department of Physics, Division of Science and Technology, University of Education, Lahore, Pakistan




CdS, electrodeposition, semiconductor, Photoelectrochemical properties, Mott-Schottky plots


Cadmium Sulphide thin films have been successfully electrodeposited on a conducting Indium-Tin-Oxide (ITO) glass substrate, with different deposition time (10 min, 20 min, and 30 min). The Scanning electron microscopy (SEM), UV-Vis spectrophotometry, X-ray diffraction (XRD), and Atomic force microscopy (AFM) were used to characterize the morphological of films obtained. Moreover, Mott–Schottky (MS) measurements and Photoelectrochemical (PEC) measurements were carried out to study their structural, optical and electrical properties respectively. XRD result points to high crystallinity oriented along (002) planes. The studies reveal that the optical transmission increases with decreasing time of deposition. Mott-Schottky and Photoelectrochemical studies indicates that the CdS thin films display n-type semiconductor, which allows used as layer in photovoltaic cell applications.


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Ezzeldien M, Alrowaili ZA, Hasaneen MF, Synthesis of optimized ZnS/Au/ZnS multilayer films for solar cell electrode applications. Opt. Mater., 2021, 113: 110814

Elsaeedy HI, Hassan AA, Yakout HA, The significant role of ZnSe layer thickness in optimizing the performance of ZnSe/CdTe solar cell for optoelectronic applications, Opt Laser Technol., 2021, 141 : 107139

Boosagulla D, Mandati S, Allikayala R, Sarada BV, Room Temperature Pulse Electrodeposition of CdS Thin Films for Application in Solar Cells and Photoelectrochemical Cells. ECS J. Solid State Sci. Technol., 2018, 7: 440-446

Upadhyay RK, Sharma M, Singh DK, Amritphale SS, Chandra N, Photo degradation of synthetic dyes using cadmium sulfide nanoparticles synthesized in the presence of different capping agents. Separation and Purification Technology., 2012, 88 : 39-45

Garde AS, Large scale synthesis and characterization of cadmium sulfide nanoparticles by simple chemical route, Nanosystems: Physics, Chemistry, Mathematics., 2020, 11: 444 – 452

Judran HK, Yousif NA, AL-Jawad SMH, Preparation and characterization of CdS prepared by hydrothermal method, J Sol-Gel Sci Technol., 2021, 97: 48–62

Afzaal M, O'Brien P, Recent developments in II–VI and III–VI semiconductors and their applications in solar cells, J. Mater. Chem., 2006, 16: 1597–1602.

Vázquez-Monroy F, García-Barrientos A, Hoyo-Montaño JA, Valencia-Palomo G, Gómez-Pozos H, .Bernal JL, Fabrication and characterization of CdS thin film synthesized by CBD deposited from pH-controlled growth solutions for solar cells applications. Metallogr Microstruct Anal., 2016, 5: 62–68

Mammadov MN, Electrodeposition of cadmium sulfide., Int. J. Thin Film Sci. Tec 2012,1: 43-53

Sivagamai D, Priyadarshini BG, Composition dependent structural, morphological, optical and electrical properties of CdS: Co window layer grown by chemical bath deposition., Mater. Sci. Technol 2020, 3: 709-718.

Chen X, Zhang Z, Chi L, Nair AK, Shangguan W, Jiang Z. Recent advances in visible - light-driven photoelectrochemical water splitting: catalyst nanostructures and reaction systems., Nano-Micro Letters 2016, 8: 1–12

Zhang Y, Zhang F, Wang H, Wang L, Wang F, High-efficiency CdSe/CdS nanorod–based red light–emitting diodes., Opt. Express 2019, 27: 7935-7944

Grover R, Srivastava R, O Rana, AK Srivastava, KK. Maurya, KN. Sood, DS. Mehta, M N. Kamalasanan, Electroluminescence from hybrid organic–inorganic LEDs based on thermally evaporated CdS thin films., J. Lumin. 2012, 132: 330-336

Sivanand R, Chellammal S, Sambanthan Manivannan Cadmium Sulphide Nanocrystallites for Optoelectronic Devices., Mater. Sci. Forum 2019, 969: 237-241

Dabhane H, Ghotekar S, Tambade P, Pansambal S, Ananda HC Murthy, Oza R, Medhane V, A review on environmentally benevolent synthesis of CdS nanoparticle and their applications Environmental Chemistry and Ecotoxicology, J. Environ. Chem. Ecotoxicol., 3, 2021, 3: 209-219.

Salaria K, Mehta N, Krishna CR, Mehta SK, Electrochemical detection of TNT using CdS nanoparticles via cyclic voltammetry and amperometry Author links open overlay panel, Curr. Opin. Green Sustain. Chem., 2021, 4: 100166

Mendhe AC, Majumder S, Nair N, Sankapal BR, Core-shell cadmium sulphide @ silver sulphide nanowires surface architecture: Design towards photoelectrochemical solar cells, J. Colloid Interface Sci, 2021, 587: 715-726

Diaz-Grijalva OI, Berman Mendoza D, Flores-Pacheco A, López-Delgado R, Ramos-Carrazco A, Alvarez-Ramos ME, Cu-doped CdS thin films by chemical bath deposition and ion exchange., J Mater Sci Mater Electron, 2020, 3: 1722–1730.

Marathe YV, Shrivastava VS, Synthesis and application of CdS nanocrystalline thin films., Adv. Appl. Sci. Res, 2011, 2: 295 – 301.

Patra S, Mitra P, Pradhan SK, Preparation of nanodimensional CdS by chemical dipping technique and their characterization., Mater Res, 2011, 14 : 17–20

Ojo AA, Dharmadasa IM, Investigation of electronic quality of electrodeposited cadmium sulphide layers from thiourea precursor for use in large area electronics., Mater. Chem. Phys, 2016,180: 14-28

Zyoud A, Saadeddin L, Khudruj S, Hawash ZM, CdS/FTO thin film electrodesdeposited by chemical bathdeposition and by electrochemicaldeposition: A comparat, Solid State Sci, 2013, 18 : 83–90

Ismail RA, Al-Samarai AME, Ali AY, Preparation and characteristics study of CdS/macroporous silicon/c-Si double heterojunction photodetector by spray pyrolysis technique., Optik, 2018, 168: 302-312

Rondiya S, Rokade A, Gabhale B, Pandharkar S, Effect of bath temperature on optical and morphology properties of CdS thin films grown by chemical bath deposition., Energy Procedia, 2017, 110: 202–209

Aboud AA, Mukherjee A, Revaprasadu N, The effect of Cu-doping on CdS thin films deposited by the spray pyrolysis technique, J Mater Res Technol, 2019, 8: 2021–2030

Sahraei R, Shahriyar S, Majles Ara MH, Daneshfar A, Shokri N, Preparation of nanocrystalline CdS thin films by a new chemical bath deposition route for application in solar cells as antireflection coatings., Prog. Color Colorants Coat, 2010, 3: 82-90.

Al-Jawad SMH, Mousa AM, Taha WA, Investigation of optical properties of cadmium sulfide (CdS) thin films by chemical bath deposition., Um-Salama Science Journal, 2009, 6: 150-162.

Okorie O, Buba ADA, Ramalan AM, Optical and Dielectric Properties of Cadmium Sulphide Thin Film Grown Using Chemical Bath Deposition Technique., IOSR J. Appl. Phys, 2017, 9 : 82-89.

Jassim S, Abbas A, Shakban MAL, Chemical Vapour Deposition of CdS Thin Films at Low Temperatures from Cadmium Ethyl Xanthate., Egypt. J. Chem, 2021, 64: 2533-2538

Buckingham MA, Catherall AL, Hill MS, Johnson AL, Parish JD, Aerosol-Assisted Chemical Vapor Deposition of CdS from Xanthate Single Source Precursors., Cryst. Growth Des, 2017, 17: 907–912.

Loudhaief N, Labiadh H, Hannachi E, Zouaoui M, Ben Salem M, Synthesis of CdS nanoparticles by hydrothermal method and their effects on the electrical properties of Bi-based superconductors., J Superconductivity Nov Magn, 2018, 31: 2305–2312

Islam MA , Haque F , Rahman KS , Dhar N , Hossain MS, Effect of oxidation on structural, optical and electrical properties of CdS thin films grown by sputtering., Optik, 2015, 126: 3177-3180

Altiokka B, Yildirim AK, Electrodeposition of CdS Thin Films at Various pH Values., J. Korean Phys. Soc, 2018, 72: 687-691.

MarichevaJ, BereznevS, Naidu R, Maticiuc N, Improved electrodeposition of CdS layers in presence of activating H2SeO3 microadditive, Mater Sci Semicond Process., 2016, 54:. 14-19.

Zarębska K, M Skompska, Electrodeposition of CdS from acidic aqueous thiosulfate solution-Invesitigation of the mechanism by electrochemical quartz microbalance technique., Electrochim. Acta, 2011, 56 , 5731-5739

Kralji M, Mandic Z, Dui L, Inhibition of steel corrosion bypolyaniline coatings Corrosion Science., 2003, 45: 181-198

Murali KR, Kumaresan S, Prince JJ, Characteristics of CdS films brush electrodeposited on low-temperature substrates., Mater Sci Semicond Process, 2007, 10: 56-60

Aaboubi Q, Douglade J, Abenaqui X, Boumedmed R, VonHoff J, Influence of tartaric acid on zinc electrodeposition from sulphate bath., Electrochim. Acta, 2011, 56: 7885-7889.

Cao M, Li L, Zhang BL, Huang J, Tang K, Cao H, Sun Y, Shen Y, Influence of substrates on the structural and optical properties of ammonia-free chemically deposited CdS films., J. Alloys Compd, 2012, 530: 81-84.

Nagamine M, Osial M, Widera-Kalinowska J, Jackowska K, Krysinski P, Photosensitive Thin Films Based on Drop Cast and Langmuir-Blodgett Hydrophilic and Hydrophobic CdS Nanoparticles, Nanomaterials, 2020, 10: 2437

Meissner D, Memming R, Kastening B, Photoelectrochemistry of cadmium sulfide. 1. Reanalysis of photocorrosion and flat-band potential., J. Phys. Chem, 1988, 92: 3476-3483

Maiorova TL, Klyuev VG, Recombination processes in pyrolytic cadmium sulfide films., Semiconductors, 2009, 43: 292–296.

Abdulkhadar M, Thomas B, Study of dielectric properties of nano-particles of cadmium Sulphide., phys. stat. sol. (a) 1995, 150: 755-762

Montiel T, Solorza O, Sanchez H, Study of Cadmium Electrochemical Deposition in Sulfate Medium., J. Electrochem. Soc, 2000, 147: 1031-1037

Saxena N, Kalsi T, Uttam P, Kumar P, Morphological evolution in nanocrystalline CdS thin films from flowers to salt rock like structures., Opt. Mater, 2018, 84: 625–630

Fu Y, Ding Y, Zheng L, Zhu YF, Han S, Morphology-and Size-Controlled Fabrication of CdS from Flower -Like to Spherical Structures and their Application for High-Performance Photoactivity., Eur. J. Inorg. Chem, 2019, 24: 2086-2092.




How to Cite

HAMZA , D. E. .; LAMIRI, L.; TOUNSI, A. .; AZIZ, A. .; SAEED , M. A. . TIMES EFFECT ON MORPHOLOGICAL, STRUCTURAL AND OPTICAL BEHAVIORS OF CDS THIN FILMS FOR PHOTOELECTROCHEMICAL CELLS APPLICATION. Journal of Fundamental and Applied Sciences, [S. l.], v. 14, n. 3, p. 548–566, 2022. DOI: 10.4314/jfas.1242. Disponível em: https://jfas.info/index.php/JFAS/article/view/1242. Acesso em: 25 sep. 2022.